2.3 Друкарські фарби на органічних розчинниках

Короткий опис речовини відповідно до паспорту безпеки (SAFETY DATA SHEET)


SAFETY DATA SHEET

1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

GROUP NAME Solvent/nitrocellulose based ink
APPLICATION PRINTING INKS

2. HAZARDS IDENTIFICATION

Classification of the substance or mixture Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xi Irritant
R36 Irritating to eyes.
F Highly flammable.
R11 Highly flammable.
R67 Vapours may cause drowsiness and dizziness.

Information concerning particular hazards for humanand environment

The product has to be labelled due to the calculation procedure of the “General Classification guideline for preparations of the EU” in the latest valid version.

Classification system:

The classification is according to the latest editions of the EU-lists, and extended by company and literature data.

Label elements

Labelling according to EU guidelines:

The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.

3. COMPOSITION/INFORMATION ON INGREDIENTS

Volatile regulated chemicals are declared in sect. 8with ppm.

Chemical characterization:   Mixtures

Description:   Mixtures of substances listed below with nonhazardous additions.

Dangerous components:

CAS: 71-23-8 Propan-1-ol 2.5-10%
EINECS: 200-746-9 Xi R41, F R11
R67
Flam.Liq.2, H225, Eye Dam. 1, H318: STOT SE 3, H336
CAS: 1569-02-3 1-propoxypropan-2-ol 10-25%
EINECS: 216-372-4 R10
Flam.Liq.3, H226
CAS: 67-63-0 Propan-2-ol 10-25%
EINECS: 200-661-7 Xi R36, F R11
R67
Flam.Liq.2, H225, Eye Irrit. 2, H319: STOT SE 3, H336
CAS: 141-78-6 Ethyl acetate 10-25%
EINECS: 205-500-4 Xi R36, F R11
R66-67
Flam.Liq.2, H225, Eye Irrit. 2, H319: STOT SE 3, H336

Additional information: Observe that substances, which are health- or environmental harmful may be part of the product in small doses

4. FIRST AID MEASURES

Description of first aid measures:

After inhalation:   Supply fresh air; consult doctor in case of complaints.

After skin contact:   Generally the product does not irritate the skin.

After eye contact:   Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

After swallowing:   If symptoms persist, consult a doctor.

Information for doctor:

Most important symptoms and effects, both No further relevant information available.
acute and delayed
Indication of any immediate medical attention No further relevant information available.
and special treatment needed

5. FIREFIGHTING MEASURES

Extinguishing media:

Suitable extinguishing CO2, powder or water spray. Fight liger fires with water spray or alcohol
agents: resistant foam.
For safety reasons Water with full jet.
unsuitable
extinguishing agents:

Advice for fire-fighters

Protective equipment No special measures required.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Wear necessary protective equipment. Keep unprotected persons away.

Environmental precautions

Do not allow spill to enter sewers/surface or ground water.

Methods and material for containment and cleaning up

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation.

Reference to other sections

  • See Section 7 for information on safe handling.
  • See Section 8 for information on personal protection equipment
  • See Section 13 for disposal information

7. HANDLING AND STORAGE

Handling:

Precautions for safe handling Ensure good ventilation/exhaustion at the workplace.

Information about fire – and explosion protection:

Keep ignition sources away – Do not smoke.

Protect against electrostatic charges.

Conditions for safe storage, including any incompatibilities:

Storage:

Requirements to be met by storerooms and receptacles: Store in cool location.

Information about storage in one common storage facility: Not required.

Further information about storage conditions:

Keep containers tightly sealed.

Store in cool, dry conditions in well sealed receptacles.

Specific end use(s): No further relevant information available.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Additional information about design of technical facilities: No further data, see item 7.

Control parameters

Ingredients with limit values that require monitoring at workplace.

71-23-8 propan-1-ol
WEL (Great Britain) Short-term value: 625 mg/m3, 250 ppm
Long-term value: 500 mg/m3, 200 ppm
GV (Denmark) Sk
500 mg/m3, 200 ppm
H
67-63-0 propan-2-ol
WEL (Great Britain) Short-term value: 1250 mg/m3, 500 ppm
Long-term value: 999 mg/m3, 400 ppm
GV (Denmark) 490 mg/m3, 200 ppm
141-78-6 ethyl acetate
WEL (Great Britain) Short-term value: 400 ppm
Long-term value: 200 ppm
GV (Denmark) 540 mg/m3, 150 ppm
64-17-5 ethanol
WEL (Great Britain) 1920 mg/m3, 1000 ppm
GV (Denmark) 1900 mg/m3, 1000 ppm

Additional information: The lists valid during the making were used as basis.

Exposure controls

Personal protective equipment:

General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.

Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
In case of brief exposure or low pollution use respiratory filter device.

Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration ofpenetration times, rates of diffusion and the degradation.

Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Neoprene gloves.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.

Eye protection: Tightly sealed goggles

9. PHYSICAL AND CHEMICAL PROPERTIES

Physical State Liquid.
Colour According to product specification.
Odour Characteristic
Solubility Soluble in most organic solvents.

Physical and chemical parameters

Parameter Value / Unit
Boiling point ~ 77 °C
Flash point >-4 °C
Ignition temperature: 270 °C
Self-igniting: Product is not self self-igniting.
Danger of explosion: Product is not explosive. However, formation of explosive air/vapour mixtures
are possible
Explosion limits:
Lower: 2.1 Vol %
Upper: 15.0 Vol %
Vapour pressure at 97 hPa
20°C
Density at 20°C ~ 0,95 g/cm³ (Theory/Teori)
Solubility in/Miscibility Not miscible or difficult to mix
with water
Viscosity at 20°C 25-35 s, Ford Cup 4
Solvent content: 65-70%
Organic solvents:
Solid content: 30-35%

10. STABILITY AND REACTIVITY

Reactivity Chemical stability Thermal decomposition/conditions to be avoided: No decomposition if used according to specifications. Possibility of hazardous reactions: No dangerous reactions known.

Conditions to avoid:
No further relevant information available.

Hazardous decompositions products:
No dangerous decomposition products known.

11. TOXICOLOGICAL INFORMATION

•Information on toxicological effects •Acute toxicity 71-23-8 propan-1-ol ORAL LD50 DERMAL LD50 1850 mg/kg (rat) 5040 mg/kg (rabbit) 67-63-0 propan-2-ol ORAL LD50 DERMAL LD50 Inhalative LC50/4 h 5045 mg/kg (rat) 130 mg/l (rat)2800 mg/kg (rabbit) 141-78-6 ethyl acetate ORAL LD50 DERMAL LD50 5260 mg/kg (rat) 1600 mg/kg (rabbit) •Primary irritant effect: •On the skin: No irritant effect •On the eye: Irritating effect •Sensitisation: No sensitizing effects known.

The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for Preparations as issued in the latestversion.

12. ECOLOGICAL INFORMATION

Toxicity

Aquatic toxicity: No further relevant information available.

Persistence and degradability: No further relevant information available.

Behaviour in environmental systems:
Bioaccumulative potential: No further relevant information available.

Mobility in soil: No further relevant information available.

Additional ecological information:

General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. · Results of PBT and vPvB assessment · PBT: Not applicable. · vPvB: Not applicable. · Other adverse effects: No further relevant information available.

13. DISPOSAL CONSIDERATIONS

· Waste treatment methods · Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage system.

European waste catalogue

08 03 12* Waste ink containing dangerous substances · Uncleaned packaging: · Recommendation: Disposal must be made according t o official regulations.

14. TRANSPORT INFORMATION

UN Number ADR, IMDG, IATA UN1210 UN proper shipping name ADR IMDG, IATA 1210 Printing ink, special provision 640D Printing ink Transport hazard class(es) ADR. IMDG, IATA Class 3 Flammable liquids. Label 3 Packing group ADR, IMDG, IATA II Environmental hazards: Marine pollutant: No Special precautions for users Danger code (Kemler) EMS Number Warning: Flammable liquids 33 F-E, S-D Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. Transport/Additional information: ADR Tunnel restriction code D/E

15. REGULATORY INFORMATION

Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16. OTHER INFORMATION

The safety data sheet has been prepared on the basis of known data at the time of preparation. It is the responsibility of the recipient of this safety data sheet to ensure thatinformation given here is read and understood by all who use, handle, dispose of or in any way come in contact with the product. Information is given to the best of our knowledge, but without any guarantee regarding use. The intent of this safety data sheet is to give a description of the product with regard to safe storage, handling and use. Information given applies only tothe product itself, and not in combination with other products or in any processed form, unless this is specified in the text.